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Brief Biography of Robert Bergman, University of California
at Berkeley
Robert G. Bergman was born in Chicago, Illinois, on May 23, 1942.
After completing his undergraduate studies in chemistry at Carleton
College in 1963, he received his Ph.D. at the University of Wisconsin
in 1966 under the direction of Jerome A. Berson. Bergman spent 1966-67
as a North Atlantic Treaty Organization Fellow in Ronald Breslow's
laboratories at Columbia, and following that went to the California
Institute of Technology as a Noyes Research Instructor. He was promoted
to assistant professor in 1969, associate professor in 1971, and
full professor in 1973. He accepted an appointment as a professor
of chemistry at the University of California, Berkeley, in July
1977, and moved his research group to Berkeley about a year later.
While he was an assistant professor, Bergman received an Alfred
P. Sloan Fellowship (1969) and a Camille and henry Dreyfus Foundation
Teacher-Scholar Award (1970). He received a California Institute
of Technology Student Government Award for Excellence in Teaching
in 1978. In 1984, Bergman was elected to membership in the National
Academy of Sciences and the American Academy of Arts and Sciences.
He is the second recipient of the American Chemical Society Award
in Organometallic Chemistry (1986), and received an Arthur C. Cope
Scholar Award from the ACS in Fall, 1987. In 1991, he was granted
a MERIT award from the National Institutes of Health. He received
the E.O. Lawrence Award in Chemistry from the U.S. Department of
Energy in 1994. He received the American Chemical Society Arthur
C. Cope Award in 1996, and a Guggenheim Fellowship as well as the
American Institute of Chemists Chemical Pioneer Award in 1999. Bergman
has been a member of the Editorial Advisory Boards of the Journal
of Organic Chemistry (1980-83 and 1996-present), Organometallics
(1981-84 and 1992-95), Chemical Reviews (1981-84), the International
Journal of Chemical Kinetics (1986-89), the Journal of the American
Chemical Society (1990-95), Synlett (1989- present), and Organic
Letters (1999- present).
Bergman was trained as an organic chemist and spent the first part
of his independent career at Caltech investigating the mechanisms
of organic reactions. He also developed the methods for the generation
and study of unusually reactive molecules, such as 1,3-diradicals
and vinyl cations. In 1972 he discovered the thermal cyclization
of cis-1,5-hexadiyne-3-enes to 1,4-dehydrobenzene diradicals. In
the 1980's this transformation of ene-diynes was identified as a
crucial DNA-cleaving reaction in several antibiotics that bind to
nucleic acids, and the ene-diyne reaction is now commonly referred
to as the "Bergman cyclization." In the mid-1970s, Bergman's
research broadened to include organometallic chemistry. Since moving
to Berkeley he has made contributions to the synthesis and chemistry
of several types of organotransition metal complexes and to improving
our understanding of the mechanisms of their reactions. In this
area, he has focused on migratory insertion and oxidative addition
reactions, the chemistry of dinuclear complexes, the investigation
of organometallic compounds having metal-oxygen and -nitorgen bonds,
and the reactions of organotransition metal enolates. He is probably
best known for his discovery of the first soluble organometallic
complexes that undergo intermolecular insertion of transition metals
into the carbon-hydrogen bonds of alkanes, and the use of liquefied
noble gas solvents in the study of these reactions.
Internet: http://chem.berkeley.edu/people/faculty/bergman/bergman.html
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